Just follow these simple steps
1. Create a Shortcut to Gtalk on your DeskTop.2. Right Click on it & Open Properties
3. In Target - Change /startmenu with /nomutex and click Apply.
4. Now click on GTalk icon on your desktop and every time you click, a new instance of gtalk will open. Now You can run 2 or more GTalk accounts on your system at once.
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